离子液体溶解天然高分子材料及绿色纺丝技术研究综述

中国科学院过程工程研究所, 中国科学院绿色过程与工程重点实验室, 北京 100090
基金项目:973国家重点基础研究发展计划项目(2015CB251403)
国家自然科学基金委重大研究计划重点支持项目(91434203)
国家自然科学基金项目(21576262)
2014年中科院"引进杰出技术人才"支持项目
中图分类号:O645.13;O635;TS102

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100090, China
Received Date:2016-01-12
Available Online:2016-03-15
CLC number:O645.13;O635;TS102

摘要:针对离子液体溶解纤维素、甲壳素/壳聚糖、角蛋白及其他天然高分子化合物的构效关系、溶解机理及纺丝过程的研究现状进行了综述,认为,离子液体在溶解天然高分子材料及干喷湿纺纺丝方面显示出独特的优势,为发展新一代绿色纺丝技术提供了新途径.然而离子液体溶解纺丝要实现大规模工业化应用,尚需解决一些关键问题,如溶解机理的深入研究、功能化离子液体的设计、溶液流变性及可纺性的研究、离子液体的再生纯化等.
- 离子液体/
- 天然高分子材料/
- 溶解机理/
- 干喷湿纺工艺
Abstract:The structure-activity relationship, dissolution mechanism and spinning processes of dissolving cellulose, chitin/chitisan, keratin and other natural spinning polymer materials in ionic liquids (ILs) were reviewed. It was concluded that ILs as a class of green and prominent solvents in dissolving natural spinning polymer materials and dry-jet wet spinning provided a new approach to the new generation of green spinning technology. But in order to realize wide industrial application some key scientific problems of ILs spinning should be solvedincluding thorough research of the dissolution mechanism, further design of the functionalized ILs, exploration of the conditions of rheological properties and spinnability, and the recycling of ILs.
- ionic liquid/
- natural polymer material/
- dissolution mechanism/
- dry jet-wet spinning process
1. [1]
  WANG H,GURAU G,ROGERS R D.Ionic liquid processing of cellulose[J].Chem Soc Rev,2012,41(4):1519.
2. [2]
  PINKERT A,MARSH K N,PANG S S,et al.Ionic liquids and their interaction with cellulose[J].Chem Rev,2009,109(12):6712.
3. [3]
  BARTLETT D H,AZAM F.Chitin,cholera,and competence[J].Science,2005,310(5755):1775.
4. [4]
  陈莹,王宇新.角蛋白及其提取[J].材料导报,2002,16(12):65.
5. [5]
  贾如琰,何玉凤,王荣民,等.角蛋白的分子构成、提取及应用[J].化学通报,2008,4:265.
6. [6]
  TSIOPTSIAS C,STEFOPOULOS A,KOKKINOMALIS I,et al.Development of micro-and nano-porous composite materials by processing cellulose with ionic liquids and supercritical CO₂[J].Green Chem,2008,10(9):965.
7. [7]
  EDGAR K J,BUCHANAN C M,DEBENHAM J S,et al.Advances in cellulose ester performance and application[J].Prog Polym Sci,2001,26(9):1605.
8. [8]
  SWATLOSKI R P,SPEAR S K,HOLBREY J D,et al.Dissolution of cellose with ionic liquids[J].J Am Chem Soc,2002,124(18):4974.
9. [9]
  UPDEGRAFF D M.Semimicro determination of cellulose inbiological materials[J].Anal Biochem,1969,32(3):420.
10. [10]
  FINK H P,WEIGEL P,PURZ H J,et al.Structure formation of regenerated cellulose materials from NMMO-solutions[J].Prog Polym Sci,2001,26(9):1473.
11. [11]
  FISCHER S,VOIGT W,FISCHER K.The behaviour of cellulose in hydrated melts of the composition LiX·nH₂O (X=I^-,NO₃^-,CH₃COO^-,ClO₄^-)[J].Cellulose,1999,6(3):213.
12. [12]
  FISCHER S,LEIPNER H,TH MMLER K,et al.Inorganic molten salts as solvents for cellulose[J].Cellulose,2003,10(3):227.
13. [13]
  HEINZE T,LIEBERT T.Unconventional methods in cellulose functionalization[J].Prog Polym Sci,2001,26(9):1689.
14. [14]
  XU A R,WANG J J,WANG H Y.Effects of anionic structure and lithium salts addition on the dissolution of cellulose in 1-butyl-3-methylimidazolium-based ionic liquid solvent systems[J].Green Chem,2010,12(2):268.
15. [15]
  BRANDT A,GRÄSVIK J,HALLETT J P,et al.Deconstruction of lignocellulosic biomass with ionic liquids[J].Green Chem,2013,15(3):550.
16. [16]
  ZHAO H,BAKER G A,SONG Z Y,et al.Designing enzyme-compatible ionic liquids that can dissolve carbohydrates[J].Green Chem,2008,10(6):696.
17. [17]
  ERDMENGER T,HAENSCH C,HOOGENBOOM R,et al.Homogeneous tritylation of cellulose in 1-butyl-3-methylimidazolium chloride[J].Macromol Biosci,2007,7(4):440.
18. [18]
  ZAVREL M,BROSS D,FUNKE M,et al.High-throughput screening for ionic liquids dissolving (ligno-)cellulose[J].Bioresource Technol,2009,100(9):2580.
19. [19]
  FENG L,CHEN Z L.Research progress on dissolution and functional modification of cellulose in ionic liquids[J].J Mol Liq,2008,142(1):1.
20. [20]
  KLEMM D,HEUBLEIN B,FINK H P,et al.Cellulose:fascinating biopolymer and sustainable raw material[J].Angew Chem Int Edit,2005,44(22):3358.
21. [21]
  ZHAO Y L,LIU X M,WANG J J,et al.Effects of cationic structure on cellulose dissolution in ionic liquids:a molecular dynamics study[J].Chem Phys Chem,2012,13(13):3126.
22. [22]
  LI Y,LIU X M,ZHANG S J,et al.Dissolving process of a cellulose bunch in ionic liquids:a molecular dynamics study[J].Phys Chem Chem Phys,2015,17(27):17894.
23. [23]
  XU J L,YAO X Q,XIN J Y,et al.An effective two-step ionic liquids method for cornstalk pretreatment[J].J Chem Technol Biot,2015,90:2057.
24. [24]
  JIANG G S,YUAN Y,WANG B C,et al.Analysis of regenerated cellulose fibers with ionic liquids as a solvent as spinning speed is increased[J].Cellulose,2012,19(4):1075.
25. [25]
  HAURU L K J,HUMMEL M,MICHUD A,et al.Dry jet-wet spinning of strong cellulose filaments from ionic liquid solution[J].Cellulose,2014,21(6):4471.
26. [26]
  XIA X L,YAO Y B,ZHU X J,et al.Simulation on contraction flow of concentrated cellulose/1-butyl-3-methylimidazolium chloride solution through spinneret orifice[J].Mater Res Innov,2014,18(S2):S2-874.
27. [27]
  XIE H B,ZHANG S B,LI S H.Chitin and chitosan dissolved in ionic liquids as reversible sorbents of CO₂[J].Green Chem,2006,8(7):630.
28. [28]
  MANTZ R A,FOX D M,GREEN J M,et al.Dissolution of biopolymers using ionic liquids[J].Z Naturforsch A,2007,62(5/6):275.
29. [29]
  WU Y S,SASAKI T,IRIE S,et al.A novel biomass-ionic liquid platform for the utilization of native chitin[J].Polymer,2008,49(9):2321.
30. [30]
  YAMAZAKI S,TAKEGAWA A,KANEKO Y,et al.An acidic cellulose-chitin hybrid gel as novel electrolyte for an electric double layer capacitor[J].Electrochem Commun,2009,11(1):68.
31. [31]
  PRASAD K,MURAKAMI M-A,KANEKO Y,et al.Weak gel of chitin with ionic liquid,1-allyl-3-methylimidazolium bromide[J].Int J Biol Macromol,2009,45(3):221.
32. [32]
  WANG W T,ZHU J,WANG X L,et al.Dissolution behavior of chitin in ionic liquids[J].J Macromol Sci Part B Phys,2010,49(3):528.
33. [33]
  段先泉,徐纪刚,何北海,等.壳聚糖在1-乙基-3-甲基咪唑醋酸盐离子液体中的溶解与再生[J].化工新型材料,2011,39(4):56.
34. [34]
  朱庆松,韩小进,程春祖,等.壳聚糖在4种咪唑型离子液体中溶解性的研究[J].高分子学报,2011(10):1173.
35. [35]
  CHEN Q T,XU A R,LI Z Y,et al.Influence of anionic structure on the dissolution of chitosan in 1-butyl-3-methylimidazolium-based ionic liquids[J].Green Chem,2011,13(12):3446.
36. [36]
  XIAO W J,CHEN Q,WU Y,et al.Dissolution and blending of chitosan using 1,3-dimethylimidazolium chloride and 1-H-3-methylimidazolium chloride binary ionic liquid solvent[J].Carbohyd Polym,2011,83(1):233.
37. [37]
  梁升,纪欢欢,李露,等.氨基酸离子液体对壳聚糖溶解性能的影响[J].高分子材料科学与工程,2010,26(2):70.
38. [38]
  LI L,YUAN B,LIU S W,et al.Clean preparation process of chitosan oligomers in gly series ionic liquids homogeneous system[J].J Polym Environ,2012,20(2):388.
39. [39]
  QIN Y,LU X M,SUN N,ROGERS R D.Dissolution or extraction of crustacean shells using ionic liquids to obtain high molecular weight purified chitin and direct production of chitin films and fibers[J].Green Chem,2010,12:968.
40. [40]
  LI L,YUAN B,LIU S W,et al.Preparation of high strength chitosan fibers by using ionic liquid as spinning solution[J].J Mater Chem,2012,22(17):8585.
41. [41]
  MA B M,ZHANG M,HE C J,et al.New binary ionic liquid system for the preparation of chitosan/cellulose composite fibers[J].Carbohyd Polym,2012,88(1):347.
42. [42]
  王江波,刘建勇.羊毛角蛋白的溶解与再利用[J].毛纺科技,2011,39(8):59.
43. [43]
  XIE H B,LI S H,ZHANG S B.Ionic liquids as novel solvents for the dissolution and blending of wool keratin fibers[J].Green Chem,2005,7(8):606.
44. [44]
  IDRIS A,VIJAYARAGHAVAN R,RANA U A,et al.Dissolution and regeneration of wool keratin in ionic liquids[J].Green Chem,2014,16(5):2857.
45. [45]
  IDRIS A,VIJAYARAGHAVAN R,RANA U A,et al.Dissolution of feather keratin in ionic liquids[J].Green Chem,2013,15(2):525.
46. [46]
  IDRIS A,VIJAYARAGHAVAN R,PATTI A,et al.Distillable protic ionic liquids for keratin dissolution and recovery[J].ACS Sustain Chem Eng,2014,2(7):1888.
47. [47]
  WANG Y X,CAO X J.Extracting keratin from chicken feathers by using a hydrophobic ionic liquid[J].Process Biochem,2012,47(5):896.
48. [48]
  HAMEED N,GUO Q P.Blend films of natural wool and cellulose prepared from an ionic liquid[J].Cellulose,2010,17(4):803.
49. [49]
  LI R,WANG D.Preparation of regenerated wool keratin films from wool keratin-ionic liquid solutions[J].J Appl Polym Sci,2013,127(4):2648.
50. [50]
  王明.咪唑类离子液体用于羊毛纤维的溶解及角蛋白溶液的应用研究[D].郑州:中原工学院,2010.
51. [51]
  ZHENG S S,NIE Y,ZHANG S J,et al.Highly efficient dissolution of wool keratin by dimethylphosphate ionic liquids[J].ACS Sustain Chem Eng,2015,3:2925.
52. [52]
  PHILLIPS D M,DRUMMY L F,CONRADY D G,et al.Dissolution and regeneration of Bombyx mori silk fibroin using ionic liquids[J].J Am Chem Soc,2004,126(44):14350.
53. [53]
  PHILLIPS D M,DRUMMY L F,NAIK R R,et al.Regenerated silk fiber wet spinning from an ionic liquid solution[J].J Mater Chem,2005,15(39):4206.
54. [54]
  张慧慧,胡晨光,邵惠丽,等.丝素在离子液体中的溶解及再生丝素纤维的结构[J].高分子材料科学与工程,2011,27(7):66.
55. [55]
  王芹.蚕丝蛋白/离子液体溶液的流变学研究及再生丝蛋白材料的制备[D].上海:复旦大学,2013.
56. [56]
  汤尧旭,赵玲,覃发正,等.猪皮胶原蛋白在1-丁基-3-甲基氯代咪唑中的溶解性能[J].皮革科学与工程,2010,20(1):5.
57. [57]
  周雅文,程宝箴,邓宇,等.胶原纤维在离子液体中的溶解特性研究[J].中国皮革,2010,39(7):22.
58. [58]
  牛凤英.离子液体溶解蛋白类纤维的研究[D].大连:大连工业大学,2012.
59. [59]
  FUKAYA Y,SUGIMOTO A,OHNO H.Superior solubility of polysaccharides in low viscosity,polar,and halogen-free 1,3-dialkylimidazolium formates[J].Biomacromolecules,2006,7(12):3295.
60. [60]
  ZHAO H,JONES C L,COWINS J V.Lipase dissolution and stabilization in ether-functionalized ionic liquids[J].Green Chem,2009,11(8):1128.
61. [61]
  TANG S K,BAKER G A,ZHAO H.Ether-and alcohol-functionalized task-specific ionic liquids:attractive properties and applications[J].Chem Soc Rev,2012,41(10):4030.
62. [62]
  CHOI H M,KWON I.Dissolution of zein using protic ionic liquids:N-(2-hydroxyethyl) ammonium formate and N-(2-hydroxyethyl) ammonium acetate[J].Ind Eng Chem Res,2010,50(4):2452.
63. [63]
  FUJITA K,OHNO H.Enzymatic activity and thermal stability of metallo proteins in hydrated ionic liquids[J].Biopolymers,2010,93(12):1093.
64. [64]
  FUJITA K,MACFARLANE D R,FORSYTH M,et al.Solubility and stability of cytochrome C in hydrated ionic liquids:effect of oxo acid residues and kosmotropicity[J].Biomacromolecules,2007,8(7):2080.
65. [65]
  WANG X L,NIE Y,ZHANG X P,et al.Recovery of ionic liquids from dilute aqueous solutions by electrodialysis[J].Desalination,2012,285:205.
66. [66]
  BAI L,WANG X L,NIE Y,et al.Study on the recovery of ionic liquids from dilute effluent by electrodialysis method and the fouling of cation-exchange membrane[J].Sci China Chem,2013,56(12):1811.
67. [67]
  孙璠,徐民,李克让,等.甲壳素和壳聚糖在离子液体中的溶解与改性[J].化学进展,2013,25(5):832.
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沈阳化工大学材料科学与工程学院沈阳 110142

离子液体溶解天然高分子材料及绿色纺丝技术研究综述

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

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通讯作者:陈斌, bchen63@163.com

离子液体溶解天然高分子材料及绿色纺丝技术研究综述

English Abstract

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

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离子液体溶解天然高分子材料及绿色纺丝技术研究综述

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

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通讯作者:陈斌, bchen63@163.com

离子液体溶解天然高分子材料及绿色纺丝技术研究综述

English Abstract

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

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