类沸石咪唑酯骨架化合物ZIF-67的超声波辅助快速合成及其超级电容性能研究

郑州轻工业学院材料与化学工程学院, 河南郑州 450001
基金项目:国家自然科学基金项目（21301159）；河南省教育厅重点项目（15A150083）
中图分类号:O631.1

Research on ultrasonic assisted rapid synthesis of zeolitic imidazolate framework-67(ZIF-67) and its supercapacitor performance

College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China
Received Date:2016-10-27
Available Online:2017-09-15
CLC number:O631.1

摘要:通过超声波辅助的方法，在较短时间内合成大量粒径可控的ZIF-67材料.利用XRD和SEM对合成的ZIF-67进行结构表征和形貌分析，并对其进行氮气等温吸脱附测试，结果表明：该方法制备的ZIF-67具有更高的结晶度、规整的菱形十二面体形貌，以及较高的孔隙度和比表面积.将其作为超级电容器电极材料，利用循环伏安、恒流充放电等电化学测试方法研究其电化学性能，结果表明：当电流密度为0.5 A/g时，超声波辅助合成的ZIF-67比电容为93 F/g，大于静置条件下合成的ZIF-67；当电流密度为1 A/g时，超声波辅助合成的ZIF-67充放电循环1000次后，其电容保持率为98.6%，具有优异的循环稳定性.
- ZIF-67/
- 超声波辅助合成/
- 超级电容性
Abstract:A large amount of size tunable zeolitic imidazolate framework-67 (ZIF-67) was synthesized in a shot time with ultrasonic assisted method. The structure and morphology of synthesized materials were characterized with XRD and SEM. Nitrogen adsorption-desorption technique was also used to characterize the synthesized ZIF-67.Results showed that the ZIF-67 prepared by this method had higher crystallinity, regular rhombic dodecahedral morphology, and higher porosity and specific surface area.As supercapacitor electrode materials, cyclic voltammetry (CV) and galvanostatic charge/discharge (GCD) measurements were carried out to test the electrochemical performance of synthesized materials.The results showed that ZIF-67 synthesized by ultrasonic assisted method delivered a specific capacitance of 93 F/g at 0.5 A/g, which was much higher than that of ZIF-67 synthesized under static condition.When current density was 1 A/g,the specific capacitance of ZIF-67 synthesized by ultrasonic assisted mehtod could be retained to 98.6% of the initial value after 1000 cycles, demonstrating the excellent cycling stability.
- ZIF-67/
- ultrasonic assisted synthesis/
- supercapacitor performance
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沈阳化工大学材料科学与工程学院沈阳 110142

类沸石咪唑酯骨架化合物ZIF-67的超声波辅助快速合成及其超级电容性能研究

Research on ultrasonic assisted rapid synthesis of zeolitic imidazolate framework-67(ZIF-67) and its supercapacitor performance

计量

通讯作者:陈斌, bchen63@163.com

类沸石咪唑酯骨架化合物ZIF-67的超声波辅助快速合成及其超级电容性能研究

English Abstract

Research on ultrasonic assisted rapid synthesis of zeolitic imidazolate framework-67(ZIF-67) and its supercapacitor performance

目录

类沸石咪唑酯骨架化合物ZIF-67的超声波辅助快速合成及其超级电容性能研究

Research on ultrasonic assisted rapid synthesis of zeolitic imidazolate framework-67(ZIF-67) and its supercapacitor performance

计量

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通讯作者:陈斌, bchen63@163.com

类沸石咪唑酯骨架化合物ZIF-67的超声波辅助快速合成及其超级电容性能研究

English Abstract

Research on ultrasonic assisted rapid synthesis of zeolitic imidazolate framework-67(ZIF-67) and its supercapacitor performance

目录